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A theoretical study of substituent effects on the structure of isolated and condensed three-membered rings. A comparison between radicals and parent hydrocarbons

✍ Scribed by Roger Arnaud; Robert Subra; Vincenzo Barone

Publisher
Springer
Year
1998
Tongue
English
Weight
481 KB
Volume
99
Category
Article
ISSN
1432-2234

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Substituent effect on electron affinity,
Substituent effect on electron affinity, gas-phase basicity, and structure of monosubstituted propynyl radicals and their anions: A theoretical study
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## Abstract The substituent effect of electron‐withdrawing groups on electron affinity and gas‐phase basicity has been investigated for substituted propynl radicals and their corresponding anions. It is shown that when a hydrogen of the α‐CH~3~ group in the propynyl system is substituted by an elec