𝔖 Bobbio Scriptorium
✦   LIBER   ✦

A theoretical study of stationary state living polymerization with spontaneous chain transfer and transfer to monomer

✍ Scribed by S.C. Jain; V.S. Nanda


Book ID
103071242
Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
183 KB
Volume
13
Category
Article
ISSN
0014-3057

No coin nor oath required. For personal study only.

✦ Synopsis


Al~tract--ln living polymers, theoretical studies so far have been concerned with the study of the effect of chain transfer to monomer or of the effect of spontaneous chain transfer on the molecular size distribution. The simultar~ous effect of both types of transfer has not been considered in any detail. In this paper we discuss this problem with the stationary state approximation. The characteristics of the two chain transfer mechanisms for the stationary state and non-stationary state polymers are examined by considering some typical examples.


πŸ“œ SIMILAR VOLUMES


Theoretical study of chain transfer in a
✍ Litvinenko, Galina I. ;Arest-Yakubovich, Alexander A. πŸ“‚ Article πŸ“… 1993 πŸ› Wiley (John Wiley & Sons) βš– 416 KB

## Abstract The main factors determining molar mass characteristics of copolymers formed in nonterminating copolymerization under the conditions of chain transfer to solvent are studied theoretically. The dependences of the mean polymerization degrees on conversion and monomer feed composition for

Ruthenium(III) catalysis in polymerizati
✍ Rajesh Tiwari; S. K. Upadhyay; J. S. P. Rai πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 English βš– 188 KB

## Abstract The kinetics of ruthenium(III) catalyzed polymerization of vinyl monomers (M) (methyl‐, ethyl‐, and butylacrylates) by charge‐transfer mechanism with aminoalcohols (AA) (namely, ethanol‐, diethanol‐, and triethanol amines) and carbontetrachloride in dimethylsulfoxide medium have been st

The incorporation of side reactions into
✍ Gerhard Zifferer; Oskar Friedrich Olaj πŸ“‚ Article πŸ“… 1996 πŸ› John Wiley and Sons 🌐 English βš– 805 KB

## Abstract A procedure is developed that allows the calculation of chain length distributions of polymers prepared by periodic modulation of the initiation process, considering termination by disproportionation __and__ chain transfer. For the case of a (pseudostationary) laserpulse initiated polym