A Theoretical Rationalization of the Asymmetric Induction in Sulfinyl-Directed [5C + 2C] Intramolecular Cycloadditions
✍ Scribed by López, Fernando; Castedo, Luis; Mascareñas, José L.
- Book ID
- 127241111
- Publisher
- American Chemical Society
- Year
- 2003
- Tongue
- English
- Weight
- 224 KB
- Volume
- 68
- Category
- Article
- ISSN
- 0022-3263
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The intramolecular 1,3-dipolar cycloaddition reactions of chiral morpholinone-derived azomethine ylides with tethered alkenes and alkynes have been investigated by semi-empirical methods and ab initio quantum mechanics. The observed ecient direction of the asymmetric induction in the 1,3-dipolar cyc
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