MNDO calculations indicate that substituted phosphines (PR,) and amines (NR,) are capable of providing considerable stabilization to silicenium ions. Ab initio calculations have been used to survey the ability of simple first (Li + F)"' \_\_\_\_ and second row (P e C1)3 substituents to stabilize tri
✦ LIBER ✦
A theoretical investigation of α-substituted silicenium ions.
✍ Scribed by Yitzhak Apeloig; Paul v.R. Schleyer
- Book ID
- 104235888
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- French
- Weight
- 250 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0040-4039
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To a hydrogenation vessel. filled with Raney Cobalt catalyst (Cr promoted. Grace 2724. pretreated with hydroxide. YO0 g) and wafer (22.5 L) was iidded DAB-r/mdr-(CN), (450 g) dissolved in methanol. Subsequentl! the mixture was hydrogenated at 40 atm hydrogen pressure at 70 C for 1 h. The cooled reac