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A theoretical investigation of the reaction mechanism for hydrogenated furan formation under Prins reaction conditions in trifluoroacetic acid medium

✍ Scribed by R. R. Syrlybaeva, I. V. Vakulin…


Book ID
120763185
Publisher
Springer-Verlag
Year
2013
Tongue
English
Weight
513 KB
Volume
109
Category
Article
ISSN
1878-5190

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The effect of the concentration of the acidic component on the rates of recyclization of 2,5-dialkylfurans to thiophenes and selenophenes was studied. On the basis of the direct correlation of log k on (Ho)l and the isotope effect of the solvent it was established that the reaction proceeds via a me