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A theoretical insight into the catalytic action in Friedel-Crafts reaction

✍ Scribed by V. Branchadell; A. Oliva; J. Bertrán


Book ID
103692717
Publisher
Elsevier Science
Year
1988
Weight
704 KB
Volume
44
Category
Article
ISSN
0304-5102

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Bismuth tris-trifluoromethanesulfonate (Bi(OT]93) was found to be a novel catalyst for the Friedel-Crafts acylation. The reactions of activated or deactivated benzenes such as fluorobenzene proceeded in high yields in the presence of a catalytic amount of Bi(OTf)3. This catalyst is water stable and