A Theoretical Insight into the Ability of Group 6 ML 5 Metal Fragments to Break the H−H Bond

A Joint Theoretical and Experimental Ins

A Joint Theoretical and Experimental Insight into the Electronic Structure of Chromophores Derived from 6H,12H-5,11-Methanodibenzo[b,f][1,5]diazocine

✍ Vincent Lemaur; Jérôme Cornil; Delphine Didier; Aline Mujawase; Sergey Sergeyev 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 German ⚖ 273 KB

## Abstract We report on the synthesis and electronic spectra of the chiral, donor‐acceptor (push‐pull) chromophores (±)‐**4** and (±)‐**5** with a 6__H__,12__H__‐5,11‐methanodibenzo[__b__,__f__][1,5]diazocine scaffold (__Scheme 1__ and __Fig. 2__). The electronic structures of these compounds were

A change of the bonding mode of the alum

A change of the bonding mode of the alumohydride group in byscyclopentadienylhydrido REM complexes: from heterometallic to homometallic hydrides. Crystal and molecular structures of [(η5-C5H5)2YB(μ2-H)AIH2·N(C2H5)3]2·C6H6, [(η5-C5H5)2Lu(μ2-H)2AIH·N(C2H5)3]2·C6H6 and [(η5-C5H5)2Lu]3(μ2-H)2(μ3-H)

✍ Sergei Ya. Knjazhanskij; Boris M. Bulychev; Oksana K. Kireeva; Vitalij K. Belsky 📂 Article 📅 1991 🏛 Elsevier Science 🌐 English ⚖ 761 KB

The individual CH bond as a Raman spectr

The individual CH bond as a Raman spectroscopic probe to the internal rotation of the CHCl2 Group in C6H5CHCl2

✍ P. J. A. Ribeiro-Claro; J. J. C. Teixeira-Dias 📂 Article 📅 1984 🏛 John Wiley and Sons 🌐 English ⚖ 673 KB

Coordination of 3,5-Diisopropyl-1,2,4-tr

Coordination of 3,5-Diisopropyl-1,2,4-triazolato and 5-Phenyltetrazolato Ligands to the [K([18]crown-6)]+ Fragment: Structural Insight into the Coordination of Nitrogen-Rich Azolato Ligands to Single Metal Centers

✍ Wenjun Zheng; Mary Jane Heeg; Charles H. Winter 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 138 KB 👁 1 views

Coordination of 3,5-Diisopropyl-1,2,4-tr

Coordination of 3,5-Diisopropyl-1,2,4-triazolato and 5-Phenyltetrazolato Ligands to the [K([18]crown-6)]+ Fragment: Structural Insight into the Coordination of Nitrogen-Rich Azolato Ligands to Single Metal Centers

✍ Wenjun Zheng; Mary Jane Heeg; Charles H. Winter 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 139 KB 👁 1 views

Chemistry of Unsaturated Group 6 Metal C

Chemistry of Unsaturated Group 6 Metal Complexes with Bridging Hydroxy and Methoxycarbyne Ligands. 6. C−E Bond Formation and C−O Bond Cleavage Processes in the Reactions of [Mo 2 (η 5 -C 5 H 5 ) 2 (μ-COMe)(μ-PCy 2 )(μ-CO)] with Several p -Block Elements (E) and Their Hydride Derivatives

✍ Esther García, M.; García-Vivó, Daniel; Ruiz, Miguel A. 📂 Article 📅 2010 🏛 American Chemical Society 🌐 English ⚖ 978 KB