## Abstract Ion Exclusion Chromatography is classically used for the separation of weak acid anions. Dilute strong acids (e.g. sulphuric or perchloric acid) or just water are used as eluents. To increase the exclusion effect, strong cation exchangers, characterized by high concentration of function
✦ LIBER ✦
A theoretical explanation for the inversion temperature
✍ Scribed by Jörg P. Schwartze; Sönke Bröcker
- Publisher
- Elsevier Science
- Year
- 2002
- Tongue
- English
- Weight
- 191 KB
- Volume
- 86
- Category
- Article
- ISSN
- 1385-8947
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The barrier to inversion in NF$ has been studied using ab initio molecular-orbital theory including geometry optimization at the correlation energy level. The barrier is predicted to be 12.6 kcal mol-'. Comparison is made to previous theoretical and experimental results.