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A theoretical approach to the role of transfer reactions in the thermal decomposition of polymers

✍ Scribed by G.G. Cameron; I.T. McWalter

Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
316 KB
Volume
17
Category
Article
ISSN
0014-3057

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✦ Synopsis

A~tract--The relative importance of intermolecular and intramolecular transfers is investigated in the thermal degradation of polymers, in particular polystyrene.

It is indicated that any mechanism for the pyrolysis behaviour of this polymer must include both modes of transfer. The model is offered as a diagnostic tool for mechanistic investigations of the thermal decompositions of polymers.

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A theoretical study of the effect of spo
A theoretical study of the effect of spontaneous transfer on the size distribution in living polymers
✍ V.S. Nanda; S.C. Jain πŸ“‚ Article πŸ“… 1970 πŸ› Elsevier Science 🌐 English βš– 535 KB

Comprehensive theoretical studies have been made on the effect of initiation and transfer to monomer on the molecular size distribution in living polymers. However, no detailed theoretical investigation involving spontaneous transfer has been reported so far. In the present paper, a study is made of