A Theoretical Approach to the Description of the Thermal Dissociation of N,N,N-Trimethylmethanaminium Halides
✍ Scribed by P. Skurski; M. Jasionowski; J. Błażejowski
- Book ID
- 110288031
- Publisher
- Springer Netherlands
- Year
- 1998
- Tongue
- English
- Weight
- 391 KB
- Volume
- 54
- Category
- Article
- ISSN
- 0022-5215
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We present a theoretical study on the dissociation reaction of N 8 azapantalene to four N 2 molecules. The process proceeds via isomerization of N 8 azapentalene to N 8 azidopentazole, which then dissociates directly into four nitrogen molecules. The calculations have determined the relative energie
The titled reagent incorporates an oxygen-centred nucleophile and a basic moietyÐin a suitably mutual orientationÐin the same molecule. It oxidises various primary benzylic bromides to the corresponding aromatic aldehydes under relatively mild conditions (MeCN/rt±50 C/6±24 h) in high yields (83±97%)