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A theoretical approach to the Birch reduction. Structures and stabilities of the radical anions of substituted benzenes

โœ Scribed by Birch, Arthur J.; Hinde, Alan L.; Radom, Leo

Book ID
118246954
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
904 KB
Volume
102
Category
Article
ISSN
0002-7863

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## Abstract In this work, we have calculated the thermodynamic parameters of the first steps of the free radical and anionic polymerizations of various unsaturated monomers, using ab initio methods of quantum chemistry. The enthalpies and entropies of polymerization were estimated assuming that the