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A tetrahedral complex of cobalt(II) and nickel(II)

✍ Scribed by A.W. Downs; B.A. Götz; A.E. McCarthy

Publisher
Elsevier Science
Year
1974
Weight
68 KB
Volume
10
Category
Article
ISSN
0020-1650

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📜 SIMILAR VOLUMES

Raman resonance effect in tetrahedral co
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A Ran-~ resonance effect has been obxrxd on trtxhedrti cob&(li) coriip!exes, usin, L m 'lrr excitin: line ~itiin the corr tour of the d-d absorption bands. An interpretation of the spcctrz is proposed in which the Ramzn scztteiing derives its intensity mainly from two excited e!ecironic shtes.

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The properties of pilocarpine as a ligand toward the halides of cobalt(II), nickel(II), copper(II), and zinc(II) were investigated. Pilocarpine behaved as a monodentate ligand, giving rise to compounds with the general formula methyl(pilocarpine)2X2. The coordinating geometry at the metal ion was ps