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A test of the interval rule in the 2D32 state of bismuth I

✍ Scribed by Esther U. Mintz


Book ID
104130669
Publisher
Elsevier Science
Year
1936
Tongue
English
Weight
470 KB
Volume
222
Category
Article
ISSN
0016-0032

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✦ Synopsis


The hyperfine structure of the line X 4722 of the arc spectrum of bismuth was investigated with a Fabry-Perot interferometer. After corrections were made for the mutual influence of the components, deviations from the Land6 interval rule were observed in the 2Da/~ state. These are accounted for by the addition of a cos ~ term to the usual law of interaction.

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Rotational contours of the (2+ 1) REMPI spectra of iodine due to resonance excitation to the [ ZlIs,z]c5d; lg Rydberg state have been recorded at room temperature. Rotational parameters, &, were estimated from the band-head structure and used to derive the band origin by spectral simulations. T.= 59