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A Template Synthesis of Polyamine Macrocycles Containing the 1,1′-Bis(2-phenol) Function

✍ Scribed by Mauro Formica; Vieri Fusi; Luca Giorgi; Mauro Micheloni; Pierangela Palma; Roberto Pontellini

Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
175 KB
Volume
2002
Category
Article
ISSN
1434-193X

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Using the 1,2-dihydro-1,2-diphosphinine
Using the 1,2-dihydro-1,2-diphosphinine ring as a template for the synthesis of new bicyclic structures and new trans-chelating bis-phosphines
✍ Ngoc Hoa Tran Huy; Pauline Chaigne; Ingrid Déchamps; Louis Ricard; François Math 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 139 KB 👁 1 views

## Abstract The 1,2‐dihydro‐1,2‐diphosphinine decacarbonylditungsten complex **1** has been used as a synthetic equivalent of the corresponding 1,2‐dianion **2**. These two 1,2‐positions can be linked by a (CH~2~)~4~ bridge to yield a [4.4.0] bicyclic structure **6** whose identity has been confirm