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A tandem carbonylation/cyclization radical process of 1-(2-iodoethyl)indoles and pyrrole

✍ Scribed by Luis D Miranda; Raymundo Cruz-Almanza; Miriam Pavón; Edith Alva; Joseph M Muchowski

Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
267 KB
Volume
40
Category
Article
ISSN
0040-4039

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✦ Synopsis

The AIBN-induced radical reaction of 1-(2-iodoethyl)indoles and pyrroles with Bu3SnH under 80 atm of CO was examined. Carbon monoxide was efficiently trapped by an alkyl radical to form an acyl radical which underwent intramolecular addition to the aromatic system to produce bicyclic aromatic ketones after in situ oxidation.

📜 SIMILAR VOLUMES

ChemInform Abstract: A Tandem Carbonylat
ChemInform Abstract: A Tandem Carbonylation/Cyclization Radical Process of 1-(2-Iodoethyl)indoles and Pyrrole.
✍ Luis D. Miranda; Raymundo Cruz-Almanza; Miriam Pavon; Edith Alva; Joseph M. Much 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 29 KB 👁 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

A tandem radical addition/cyclization pr
A tandem radical addition/cyclization process of 1-(2-iodoethyl)indoles and methyl acrylate
✍ Luis D Miranda*; Raymundo Cruz-Almanza; Miriam Pavón; Yeni Romero; Joseph M Much 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 66 KB

Benzindolizidine systems are generated in moderate yields by a hexabutylditin mediated consecutive radical addition, cyclization, oxidation process from 1-(2-iodoethyl)indoles and methyl acrylate.