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A synthetic route to poly(silyl)methanes via poly(phenylsilyl)methanes and poly(bromosily)methanes

✍ Scribed by Hager, Rudolf ;Steigelmann, Oliver ;Müller, Gerhard ;Schmidbaur, Hubert


Book ID
102790009
Publisher
Wiley (John Wiley & Sons)
Year
1989
Tongue
English
Weight
562 KB
Volume
122
Category
Article
ISSN
0009-2940

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## Abstract Isopropoxyethyne (1a) and __tert__‐butoxyethyne (1b) were polymerized using group 5 and 6 transition metal catalysts to give poly(isopropoxyethyne) (2a) and poly(__tert__‐butoxyethyne) (2b), respectively. The weight‐average molecular weight (__M̄__~w~) of the resulting poly(alkoxyethyne