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A synthetic approach to discorhabdin alkaloids: Hypervalent iodine oxidation of p-substituted phenol derivatives to azacarbocyclic spirodienones

✍ Scribed by Yasuyuki Kita; Takayuki Yakura; Hirofumi Tohma; Kazumi Kikuchi; Yasumitsu Tamura


Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
159 KB
Volume
30
Category
Article
ISSN
0040-4039

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✦ Synopsis


Hypervalent iodine oxidation of g-silylated p-substituted phenols by phenyliodosyl bis(trifluoroacetate) (PIFA) in 2,2,2-trifluoroethanol gave azacarbocyclic spirodienones in good yields.