𝔖 Bobbio Scriptorium
✦   LIBER   ✦

A Synthesis of (.+-.)-Sparteine.

✍ Scribed by Thomas Buttler; Ian Fleming


Publisher
John Wiley and Sons
Year
2005
Weight
23 KB
Volume
36
Category
Article
ISSN
0931-7597

No coin nor oath required. For personal study only.

✦ Synopsis


Abstract

For Abstract see ChemInform Abstract in Full Text.


πŸ“œ SIMILAR VOLUMES


Concise Asymmetric Synthesis of (-)-Spar
✍ Jean-Paul R. Hermet; Matthew J. McGrath; Peter O'Brien; David W. Porter; John Gi πŸ“‚ Article πŸ“… 2005 πŸ› John Wiley and Sons βš– 147 KB πŸ‘ 2 views
Synthesis of 5-,6-, and 7-deutero sparte
✍ Claus O. Meese; Thomas Ebner πŸ“‚ Article πŸ“… 1988 πŸ› John Wiley and Sons 🌐 French βš– 263 KB

Kinetically controlled 'H/'H exchange at carbon atom 5 of (-)-1.6-dehydrosparteinium monoperchlorate ua) followed by sodium borohydride or sodium borodeuteride reduction of the iminium double bond gave optically active 5,5-('H,)-sparteine 0 and 5.5,6-('Hs)sparteine (16). respectively. Under thermody