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A synthesis of 3-substituted pyrroles through the halogen-metal exchange reaction of 3-bromo-1-(triisopropylsilyl)pyrrole

✍ Scribed by Kozikowski, Alan P.; Cheng, Xue Min

Book ID
120629005
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
255 KB
Volume
49
Category
Article
ISSN
0022-3263

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πŸ“œ SIMILAR VOLUMES

3-Lithiopyrroles by Halogen-Metal Interc
3-Lithiopyrroles by Halogen-Metal Interchange of 3-Bromo-1-(triissopropylsilyl)pyrroles. Synthesis of Verucarin E and Other 3-Substituted Pyrroles. Preliminary Communication
✍ Joseph M. Muchowski; Reto Naef πŸ“‚ Article πŸ“… 1984 πŸ› John Wiley and Sons 🌐 German βš– 253 KB

## Abstract 3‐Lithio‐1‐(trimethylsilyl)pyrrole (**7**, __Schem 2__), obtained by halogen‐metal interchange from the 3‐bromo compound **2**, reacted with various electrophilic reagents to provide products, which on fluoride ion desilylation, gave 3‐substituted pyrroles in good overall yields. One su