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A Synthesis-Driven Structure Revision of Berkelic Acid Methyl Ester

✍ Scribed by Philipp Buchgraber; Thomas N. Snaddon; Conny Wirtz; Richard Mynott; Richard Goddard; Alois Fürstner

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
512 KB
Volume
120
Category
Article
ISSN
0044-8249

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Total synthesis and structural revision
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Stereospecific total synthesis of chromomoric acid C-I and C-II methyl esters and delicate elucidation of their structures have been reported. A stereospecific five-step synthesis, starting from enone 5, with one-pot threecomponent coupling and retro Diels-Alder reaction as the key reactions provide