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A synthesis and some reactions of 7-Oxabicyclo[2.2.1]heptan-2-one

✍ Scribed by Moursounidis, J; Wege, D

Book ID: 115538559
Publisher: Commonwealth Scientific and Industrial Research Organisation Publishing
Year: 1983
Tongue: English
Weight: 492 KB
Volume: 36
Category: Article
ISSN: 0004-9425
DOI: 10.1071/ch9832473

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## Abstract A new unsaturated bicyclic ether, 2‐methylene‐7‐oxabicyclo[2.2.1]heptane (4) was synthesized by successive Diels‐Alder addition of furan to acrylonitrile, hydrogenation of cyano compound 5, and Hofmann degradation of the quaternary ammonium hydrate 7 derived from the amine 6. Cationic p