𝔖 Bobbio Scriptorium
✦   LIBER   ✦

A surprising rearrangement of a carbeneethylene sulfide ylide

✍ Scribed by Eunju Lee Tae; Zhendong Zhu; Matthew S Platz


Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
263 KB
Volume
40
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis


Efficient synthesis of benzofuroquinolizine ketone 1 was accomplished in four steps from ethyl 3benzofuranacetate. The O-analogue of the Pictet-Spengler cyclization was used to form the benzofuroquinolizine ring structure as a key step.


📜 SIMILAR VOLUMES


CIDNP in the stevens rearrangement of a
✍ Hiizu Iwamura; Michiko Iwamura; Toshiaki Nishida; Masayuki Yoshida; Juzo Nakayam 📂 Article 📅 1971 🏛 Elsevier Science 🌐 French ⚖ 182 KB

We would like to report the observation of nuclear spin polarization in 1,2-diphenylethyl phenyl sulfide (I) formed by action of benzyne on dibenzyl sulfide (II). When a solution of 1-(2-carboxyphenyl)-3,3-dimethyltetrazene

A somersaulting rearrangement : formatio
✍ David W. Jones; Robert J. Marmon 📂 Article 📅 1989 🏛 Elsevier Science 🌐 French ⚖ 114 KB

Acetylene (3) is formed by the novel reaction of a foiled carbene (6). We have described the efficient (ca. 80% yield) conversion of (1; X = Br or H) into ( ) and ( ) (ratio 4.2:1) upon treatment with "BuLi.' Two mechanisms can be envisaged for the formation of the