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A Supramolecular “Ship in Bottle” Strategy for Enantiomeric Selectivity in Geminate Radical Pair Recombination.

✍ Scribed by Thomas Poon; Nocholas J. Turro; Jessica Chapman; P. Lakshminarasimhan; Xuegong Lei; Waldemar Adam; Sara G. Bosio

Book ID
101942787
Publisher
John Wiley and Sons
Year
2003
Weight
54 KB
Volume
34
Category
Article
ISSN
0931-7597

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Geminate radical pairs are formed from the a-photocleavage of aryl ketones within the supercage of zeolites which has been modified with chiral guest molecules. Herein, we report the supramolecular structure and dynamic control of both the enantiomeric selectivity and probability of the recombinatio