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A Supramolecular Hydrogen-Bonded Network as a Diffusion Barrier for Metal Adatoms

✍ Scribed by Christophe Silien; Minna T. Räisänen; Manfred Buck

Publisher: John Wiley and Sons
Year: 2009
Tongue: English
Weight: 414 KB
Volume: 121
Category: Article
ISSN: 0044-8249
DOI: 10.1002/ange.200806267

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✦ Synopsis

Abstract

Ionen hinter Gitter: Ein supramolekulares Netzwerk verändert den Mechanismus der Unterpotential(UP)‐Abscheidung von Kupfer auf einer Goldelektrode mit einer selbstorganisierten Monoschicht (SAM) als Überzug. Die laterale Diffusion der Cu‐Adatome zwischen benachbarten Zellen der Netzwerk‐SAM‐Hybridstruktur wird unterdrückt, und es kommt stattdessen zur direkten UP‐Abscheidung in die Poren des SAM‐belegten Netzwerks, in denen die Cu‐Adatome eingesperrt sind.magnified image

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