## Abstract The trisilanol 1,3,5‐(HO__i__Pr~2~Si)~3~C~6~H~3~ (5), a novel building block for applications in supramolecular chemistry, has been prepared via the intermediates 1,3,5‐(H__i__Pr~2~Si)~3~C~6~H~3~ (6) and (Cl__i__Pr~2~Si)~3~C~6~H~3~ (7). The inclusion complexes 5·0.5H~2~O, 5·bpy·0.5H~2~O
✦ LIBER ✦
A supramolecular hydrogen-bonded complex between 1,3,5-tris(diisobutylhydroxysilyl)benzene and trans-bis(4-pyridyl)ethylene
✍ Scribed by Jens Beckmann; Sanna L. Jänicke
- Publisher
- John Wiley and Sons
- Year
- 2007
- Tongue
- English
- Weight
- 526 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0268-2605
- DOI
- 10.1002/aoc.1261
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The synthesis and structural characterization of manganese, iron, and cobalt complexes of bis[di(2-pyridyl)methyl]amine (bdpma) were investigated. The bdpma ligand can give rise to mono-or dimeric complexes. Moreover, bdpma can undergo oxidative degradation leading to 1,3,3-tris(2-pyridyl)-3Himidazo