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A Superoxovanadium(V) Complex Linking the Peroxide and Dioxygen Chemistry of Vanadium

✍ Scribed by Harald Kelm; Hans-Jörg Krüger

Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
116 KB
Volume
113
Category
Article
ISSN
0044-8249

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📜 SIMILAR VOLUMES

Redox Chemistry in the Reaction of Oxova
Redox Chemistry in the Reaction of Oxovanadium(V) with Thiolate-Containing Ligands: the Isolation and Characterization of Non-Oxo Vanadium(IV) Complexes Containing Disulfide and Thioether Groups
✍ Hua-Fen Hsu; Chia-Ling Su; Neeruganti O. Gopal; Chi-Chin Wu; Wei-Cheng Chu; Yi-F 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 158 KB

## Abstract The reactions of V^V^O(O‐__i__Pr)~3~ with [PS3′]H~3~ and [PS3]H~3~ {[PS3′]H~3~ = P(C~6~H~3~‐5‐Me‐2‐SH)~3~, [PS3]H~3~ = P(C~6~H~4~‐2‐SH)~3~} led to the formation of [V^IV^(L)] [L = P2S4′ (1a), P2S4 (1b)], where L was formed by the oxidative coupling of two PS3′ or PS3 ligands by a disulf