While cyclic sulfonic acid esters, sultones, have been studied extensively3, the cyclic esters of the lower oxidation state sulfur acids, sulfinate esters, have remained relatively unknown. To date, only six alicyclic sulfinate esters have been reported 4. ; two
A sulfinyl- and sulfonyl-sulfine: novel sulfines by oxidation of a dithiocarboxylic ester
β Scribed by B. Zwanenburg; L. Thijs; J. Strating
- Publisher
- Elsevier Science
- Year
- 1968
- Tongue
- French
- Weight
- 100 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
In previous papers we showed that oxidation of thioketones (2,3) and dithiocarboxylic esters (4) with peracid represents a facile method for the conversion of the >C=S group in these molecules into the >C=S=O moiety. Although
π SIMILAR VOLUMES
SuZfines react with sulfiinyl chZoridt7s giving cx-chloroalkyl alkanethiosulfonate esters and with tkionyi: chloride giving a-chZoroalkanesulfeny7Y chZorides, both in good yieZds.
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