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A subtotal synthesis of methynolide via an electrophilic spirocyclization reaction

✍ Scribed by Bartlett, Paul A.; Mori, Ichiro; Bose, Judith A.


Book ID
127242015
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
566 KB
Volume
54
Category
Article
ISSN
0022-3263

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A tropylium-substituted cyclopropane has been prepared which is rigidly held in the "bisected" conformation. Its electrophilic reactions are also investigated. Bond length asymmetry in cyclopropanes, as induced by aromatic substituents, has recently been an object of attention in our 1aboratories.l