The effects of melting time (t melt ) and annealing time (t a ) at a temperature closer to the melting point of polyphenylene sulfide (PPS) on the multiple melting behavior of neat PPS, and PPS component in their blends have been investigated by differential scanning calorimetry (DSC). It is found t
A study on rheologic behavior of polyphenylene sulfide
โ Scribed by Canshu Hou; Baocheng Zhao; Jie Yang; Zili Yu; Qixian Wu
- Publisher
- John Wiley and Sons
- Year
- 1995
- Tongue
- English
- Weight
- 334 KB
- Volume
- 56
- Category
- Article
- ISSN
- 0021-8995
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โฆ Synopsis
Rheologic behavior of the common Ryton-type poly(pheny1ene sulfide) (PPS) and Fortron PPS has been studied using a capillary rheometer. The effects of shearing rate, shearing stress, and temperature on the apparent viscosities of PPS are discussed. The non-Newtonian index and the activation energy of the viscous flow were obtained. The results show that the apparent viscosity of the Ryton PPS decreased obviously with increase of shearing rate or shearing stress, and with increase of the temperature, the apparent viscosity is not considerably decreased. On the contrary, the apparent viscosity of the Fortron PPS is more sensitive to temperature than to shearing rate and shearing stress.
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