A study on adsorption structures of methacryloyloxyalkyl dihydrogen phosphates on silver substrates by infrared reflection absorption spectroscopy
✍ Scribed by Suzuki, M. ;Fujishima, A. ;Miyazaki, T. ;Hisamitsu, H. ;Ando, H. ;Nakahara, M. ;Yamamoto, M. ;Itoh, K.
- Publisher
- John Wiley and Sons
- Year
- 1997
- Tongue
- English
- Weight
- 200 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0021-9304
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✦ Synopsis
10-Methacryloyloxydecyl dihydrogen phosphate bands around 980 and 1080 cm Ϫ1 due to the PO 3 2Ϫ stretching (M10P) for use in dentistry has recently been noted as an vibrations were observed. These results indicate that the adhesive monomer contained in a metal primer. Although phosphate groups of both monomers are adsorbed to silver the treatment of a metal surface with primer before the appli-surfaces in the dissociated form, ϪPO 3
2Ϫ
, and form hydrophocation of resin is recognized to improve the adhesion between bic monolayers. The monolayer of M10P was found to be metal and resin, the role of M10P in the adhesion process has more durable against thermocycling in water than that of not been clarified. In this study, infrared reflection absorption M2P by IRA measurements. The roles of M10P in the metal (IRA) spectroscopy was employed to study the adsorption primer are presumably to form such a monolayer with apprestructures of M10P as well as 2-methacryloyloxyethyl dihy-ciable durability and to promote polymerization with resin drogen phosphate (M2P) on evaporated silver substrates. The monomers.