Vibrational relaxation of carbon monoxid
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Jeffrey R. Hill; Dana D. Dlott; M.D. Fayer; Kristen A. Peterson; Chris W. Rella;
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Article
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1995
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Elsevier Science
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English
β 437 KB
Vibrational relaxation of carbon monoxide bound to a series of metalloporphyrin complexes (M-(coproporphyrinate-I tetraisopropyl ester)(COXpyridine); M = Fe, Ru, Os) was measured using picosecond infrared pump-probe experiments. The vibrational relaxation rates ((1-2.5) Γ 101Β° s-1) increased with in