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A study of vibrational force constants in some transition metal-ethylene π-complexes

✍ Scribed by David C. Andrews; George Davidson; David A. Duce


Book ID
108351323
Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
391 KB
Volume
101
Category
Article
ISSN
0022-328X

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Complexes between alkaline-earth-metal ions M\*' and cyanate OCN' in aprotic solvents are studied by infrared spectrometry in the v(CN) region (2150-2250 cm-'). In dimethylsulphoxide (DMSO) and hexamethylphosphotriamide (HMPT) isocyanate MNCO ion pairs exhibit a specific v(CN) band while M(NCO)z spe