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A study of the Ti(III)-H2O2-SCN− reaction

✍ Scribed by V. Peruzzo; R.E. Hester

Book ID
104139206
Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
350 KB
Volume
20
Category
Article
ISSN
0020-1693

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✦ Synopsis

Both stop-flow and continuous flow methods have been used to study the reactions occurring when acidic solutions of Ti(III), H202 and SCN were mixed. The progress of the reactions was followed through a strong absorption at 480 nm, characterizing the radical species (SCN),Y The kinetic data are shown to be consistent with the SCN ion acting as an efficient scavenger for OH-radicals produced in the primary slow reaction between Ti(III) and Hz02.

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An improved version of a recently reported semiclassical wavepacket approach is used to compute initial state selected total integral cross sections as well as thermal rate constants for the reaction OH+H2 ---\* H20+H. The method involves treating the diatomic vibrations as well as their relative tr