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A study of the temperature dependence of the electronic spectra of alkyl cobaloximes

โœ Scribed by A. Blanco-Labra; A. Cartano; M. Chu; L.L. Ingraham

Publisher
Elsevier Science
Year
1975
Weight
531 KB
Volume
4
Category
Article
ISSN
0006-3061

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โœฆ Synopsis

The temperature dependence of the electronic spectra of the alkyl-pyridinatocobaloximes iu benzene solution was found to be due to an equilibrium existing between two forms proposed to be inner-sphere and outer-sphere coordination compounds_ Evidence is presented to rule out the possrbiiities of equilibria with pentacoordinated or dimeric forms, as well as a form with the cobalt out of the plane of the dimethylglyoxime.

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