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A Study of the OH - -Induced β -Elimination Reactions of 2-(4-Chloroethyl)pyridine, 2-(2-Chloroethyl)pyridine, 1-Methyl-2-(4-chloroethyl)pyridinium Iodide and 1-Methyl-2-(2-chloroethyl)pyridinium Iodide in Acetonitrile/Water

✍ Scribed by Alunni, Sergio; Del Giacco, Tiziana; De Maria, Paolo; Fontana, Antonella; Gasbarri, Carla; Ottavi, Laura


Book ID
126921392
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
55 KB
Volume
69
Category
Article
ISSN
0022-3263

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Borohydride reduction of piridinium salt
✍ F. Liberatore; A. Casini; V. Carelli; A. Arnone; R. Mondelli 📂 Article 📅 1971 🏛 Elsevier Science 🌐 French ⚖ 244 KB

In a previous paper (1) we reported the formation of the cycloadduct V, in the borohydride reduction of the pyridinium salt I. If the reduction is carried out at -45" in 0.8N methanolic NaOH the insoluble product IV is formed (60% yield), containing only traces of compound V. However, reductions car