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A STUDY OF THE METHYLATION OF XYLENE. THE PREPARATION OF DURENE, PENTAMETHYLBENZENE AND HEXAMETHYLBENZENE

✍ Scribed by Smith, Lee Irvin; Dobrovolny, F. J.


Book ID
121017205
Publisher
American Chemical Society
Year
1926
Tongue
English
Weight
470 KB
Volume
48
Category
Article
ISSN
0002-7863

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## Abstract In a two step reaction, hexamethylbenzene consumes two molecules of singlet oxygen to form epidioxy hydroperoxide **3**. The first step involves a [4 + 2]‐cycloaddition, which is followed by an ene‐reaction. The structure of the intermediary endoperoxide **2** has been established spect