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A study of the line width in the rotational spectrum of methylfluoride

โœ Scribed by N.J. Trappeniers; E.W.A. Elenbaas-Bunschoten

Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
391 KB
Volume
64
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

Tfie results of n study on the liae width in the pure rohtiomd spectrum of methylfluo6de are presented-The experimental v;tlues of rhe norxmdked Iine width as a function of the iine number show a makfmum at m = 16. There is good qu3litative zr.ereement with the theoretic4 results obt.&ed with the quantum mechsniul ttieoiy of Murphy and Bogs, although tiere remains a cliipancv in absolute value. An important result is that the Murphy and Boggs theory predicts quite accu&elY the temperature-dependence of the line width-

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An ESR line width study of vanadyl acetylacetonate (abbreviated as VO(acac),) in toluene has been carried out as a function of temperature at 9.5 GHz. It was found that VO(acac), was undergoing anisotropic reorientation with N-2.8 in 1 along a symmetry axis I' = l', where N is the ratio ofR,/R, and