A study of the effects of solvent on overtone frequencies
β Scribed by G. Durocher; C. Sandorfy
- Publisher
- Elsevier Science
- Year
- 1967
- Tongue
- English
- Weight
- 792 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0022-2852
No coin nor oath required. For personal study only.
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In an effort to model solute-solvent interactions, the C=O stretching frequencies of five 1-substituted 2pyrrolidinones and four other carbonyl-containing compounds were measured for 30 common solvents. These were then correlated with four empirical parameter sets and one theoretical (computational)
## Abstract Solvent effects on the nitrogen NMR shieldings of indolizine and three azaindolizines are presented for a range of thirteen solvents. The results are discussed in terms of hydrogenβbonding an solvent polarity effects. βPyridineβtypeβ nitrogen atoms show a much larger range of solvent ef