Chemical structure of polycaproamide (nylon-6), obtained by low temperature anionic polymerization of caprolactam in the presence of the sodium salt of caprolactam and carbon dioxide in solvent has been investigated. The polymer formed in a heterogeneous system, depending upon its final treatment, i
A study of the chemical and physical structure of polycaproamide obtained in anionic polymerization of caprolactam in solvent
✍ Scribed by P. Biernacki; M. Włodarczyk
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 771 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0014-3057
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A~tntct--Molecular weight of polycaproamide obtained by anionic polymerization of caprolactam in solution in the presence of sodium caprolactam and carbon dioxide has been investigated by absolute methods. Number average molecular weights were determined by osmometry. Weight average molecular weight
Molecular weight distribution has been investigated for polycaproamide obtained in lowtemperature, anionic polymerization of caprolactam in the presence of the sodium salt of caprolactam and carbon dioxide in solvent; fractionation has been performed at 25 ° using phenol-tetrachloroethane as solvent
## NOPSlS In this study, bis t-caprolactam bis-diphenyl methane diisocyanate polypropylene glycol 1000 used as the macroactivator was prepared and well characterized prior to use. The anionic polymerization of e-caprolactam with the macroactivator as a function of the macroactivator concentration