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A study of the Ce(III)/Ce(IV) redox couple for redox flow battery application

✍ Scribed by B Fang; S Iwasa; Y Wei; T Arai; M Kumagai

Book ID
108317860
Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
155 KB
Volume
47
Category
Article
ISSN
0013-4686

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The characteristics of the Ce(III)/Ce(IV) redox couple in methanesulfonic acid were studied at a platinum disk electrode (0.125 cm 2 ) over a wide range of electrolyte compositions and temperatures: cerium (III) methanesulfonate (0.1-1.2 mol dm -3 ), methanesulfonic acid (0.1-5.0 mol dm -3 ) and ele

A study of the V(II)/V(III) redox couple
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The electrochemical behaviour of the V(III)/V(II) redox couple has been investigated at glassy carbon electrodes using cyclic voltammetry. The oxidation/reduction is found to be electrochemically irreversible with a value k" = 1.2 X 10m4 at pH = 4. A slight trend in k" with pH is observed. Electrode