A study of the behaviour of solid-state membrane electrodes: Part III. A model for the response time
โ Scribed by J. Buffle; N. Parthasarathy
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- English
- Weight
- 755 KB
- Volume
- 93
- Category
- Article
- ISSN
- 0003-2670
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โฆ Synopsis
A model is Droposed to explain the response time of solidstate membrane electrodes, in the range of potential-time curves corresponding to seconds or minutes. Several causes of slow response time are considered.
In the range of milliseconds to seconds, diffusion seems to be the rare-determining factor, but for times exceeding about 10s. dissolution or crystallization
๐ SIMILAR VOLUMES
The model of an inhomogeneous altered surface layer of the glass, formed due to its interaction with water solutions containing potentialdetermining ions, is presented. An ion interdiffusion over sublayers involves the appearance of some quasi-steady state potential levels of the glass electrodes (G