A study of the atmospheric reaction of CH3S with O3 as a function of temperature
✍ Scribed by E Martı́nez; J Albaladejo; A Notario; E Jiménez
- Book ID
- 114377164
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- English
- Weight
- 158 KB
- Volume
- 34
- Category
- Article
- ISSN
- 1352-2310
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## Abstract A laser flash photolysis–resonance fluorescence technique has been employed to investigate the kinetics of the reaction of ground state oxygen atoms, O(^3^__P__~J~), with (CH~3~)~2~SO (dimethylsulfoxide) as a function of temperature (266–383 K) and pressure (20–100 Torr N~2~). The rate
The order of the combination reaction CH3 4 O2 has been shown to lie bet;Keen two and three throughout the pressure range from 30 to 380 torr at 22 rE Z°C, and the limiting value of the second order rate constant at high pressure is (2.7i0.2) X 108 Like moIe'I se& \_