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A study of ring cleavages in the gas-phase reactions of M+ (M = Fe, Co, Ni) with the carbosilane ring compound c-SiC5H12

โœ Scribed by Asgir Bjarnason; Ingvar Arnason; Douglas P. Ridge

Publisher
John Wiley and Sons
Year
1993
Tongue
English
Weight
285 KB
Volume
28
Category
Article
ISSN
1076-5174

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โœ Dr. Asgeir Bjarnason; Prof. Dr. Ingvar Arnason ๐Ÿ“‚ Article ๐Ÿ“… 1992 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 276 KB ๐Ÿ‘ 2 views

When starting with racemates, OY,,,,, = -l)i([j" + I ) , while for a sample ofcomposition (tl, I ) OY,,, = j([jd + 1) -2(/k/41'2)!tl(/1 -1). The optical yield can be related to the thermodynamic chirdl recognition. AAG = -RT1nl.i. as /j = [(I + OY)/(l -OY]' when d = l = I = 0.5 (0 s OY < 1 ). [12]