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A study of nickel passivity by nuclear microanalysis of O16 and O18 isotopes

โœ Scribed by J. Siejka; C. Cherki; J. Yahalom


Publisher
Elsevier Science
Year
1972
Tongue
English
Weight
796 KB
Volume
17
Category
Article
ISSN
0013-4686

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โœฆ Synopsis


The passivity of nickel in 1 N HISOl was investigated by using a nuclear microanalysis technique for the determination of Ole and O** isotopes on the metal surface. It was established by 01* tracing that the first monolayer of oxygen has a marked effect on the passivity of the metal. Further thickening of the mm up to a maximum of about 5 monolayers seems to control the anodic. current by an ion-transfer mechanism. The total quantity of oxygen found on the samples after their removal from the solution is independent of the polarization potential, due probably to further oxidation in the atmosphere. R6sum&Etude de la passivite du nickel dans HISO 1 N au moyen d'une technique nucl6aire de microanalyse, en vue de la d&rmination des isotopes 01* et 018 sur la surface m&allique. Il a et6 &abli par le traceur 0Z8 que la premiere couche monomol6culaire d'oxyg&ne a une influence marquee sur la passivite du m&al. De plus, l'6paississement du film jusqu'il un maximum d'environ 5 couches monomol&ulaires, semble impliquer le controle du courant anodique par un m&u&me de transfert ionique. La quantite totale d'oxygcne trouv6e sur les 6chantillons apr&s leur separation de la solution est independante du potentiel de polarisation, probablement du fait d'une oxydation ult&ieure par l'atmosph&re. Zusannn~--Mitts einer Tracer-Methode zur Bestimmung von O'* und Ols auf der Metalloberfhiche wurde die Passivitgt von Nickel in 1 N HISOl untersucht. Auf diese Weise konnte festgestellt werden, dass die erste Sauerstoff-Monoschicht einen ausgeprlgten Einfluss auf die Passivitat des Metalls hat. Weiteres Wachstum der Schicht bis zu 5 Monoschichten scheint den anodischen Strom ebenalls durch einen Ioneniibertragungsmechanismus zu kontrollieren. Die totale Sauerstoffmenge, die man nach dem Herausnehmen der Proben aus der Losung auf deren OberfRche fand, war vom Polarisationspotential unabhangig, vermutlich wegen einer Weiteroxydation an der Luft.


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