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A study of light-heavy mass type molecules reacting with a solid surface

✍ Scribed by Shlomo Ron; Yaakov Shima; Michael Baer

Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
377 KB
Volume
116
Category
Article
ISSN
0009-2614

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✦ Synopsis

Some features of a diatomic molecule interacting with a solid surface were studied employing the classical trajectory method. The focus was @rdy on the light-heavy (LH) mass-combination type molecule with emphasis on reactive (exchange) and dissociative processes. Two typical _LH molecule features were considered in detail; the large entrance channel angle yB ( = 170Β°) and the non-existence of the dissociative charmeL It was found that the reason for both is the same, but the existence of one is not a necessary condition for the appearan ce of the other_ A simple model was suggested to explain the inability of LH to dissociate.

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