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A study of intermolecular vibrational frequencies of phenol·(H2O)3 by spectral hole burning spectroscopy

✍ Scribed by M. Schmitt; H. Müller; K. Kleinermanns

Book ID
103032884
Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
246 KB
Volume
218
Category
Article
ISSN
0009-2614

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✦ Synopsis

The vibronic spectrum of the phenol. (HsO)s complex is obtained by persistent spectral hole burning. The population of the neutral complex is depleted by tuning a hole burning laser to a strong absorption line of the complex. The depopulation is probed by the decrease of fluorescence intensity induced by a second laser. Only transitions which share a common ground state level with the hole burning laser are recorded. Twelve intermolecular frequencies have been found in the region O-220 cm-' relative to the electronic origin of the complex.

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