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A study of intermixing in perovskite superlattices by simulation-supported cs-corrected HAADF-STEM

✍ Scribed by Hillebrand, Reinald ;Pippel, Eckhard ;Hesse, Dietrich ;Vrejoiu, Ionela


Book ID
105366536
Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
850 KB
Volume
208
Category
Article
ISSN
0031-8965

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✦ Synopsis


Abstract

In this paper, we present and interpret high‐angle annular dark field scanning transmission electron microscopy (HAADF‐STEM) images of La~0.7~Sr~0.3~MnO~3~/SrRuO~3~ superlattices. The images were taken in a probe‐corrected (c~s~ = 0) FEI microscope at 300 kV. We developed a simulation‐based technique to evaluate possible intermixing at the interfaces via Z‐contrast. The experimental and simulated image intensities across the interfaces are directly compared, where the gradients in the models are systematically varied. Different gradients in different sub‐lattices at the interfaces can clearly be distinguished by a best fit criterion.

magnified image

Coloured HAADF‐STEM image (V = 300 kV, c~s~ = 0) of a La~0.7~Sr~0.3~MnO~3~/SrRuO~3~ layer structure.