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A study of fatty acid methyl esters with epoxy or alkyne functionalities

โœ Scribed by Johan Samuelsson; Mats Johansson


Book ID
107484912
Publisher
Springer-Verlag
Year
2001
Tongue
English
Weight
103 KB
Volume
78
Category
Article
ISSN
0003-021X

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## d E . U c c i a n i * Epoxidation of monounsaturated fatty acid methyl esters with an hydroperoxide and a catalyst was undertaken. Methyl oleate. elaidate, petroselinate, erucate, ricinoleate and 10-undecenoate were tested with cumyl-and tert-butylhydroperoxide. The heterogeneous alumina suppor

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a y a n a \* Methyl esters of undecenoic, oleic, erucic, linoleic, gorlic, ricinoleic, 12hydroxystearic, 9,10-dihydroxystearic, 12-ketostearic and 9,lO-epoxystearic acids were reduced to alcohols by refluxing with sodium borohydride in t-butanol-methanol. The products were found by chromatographic a