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A study of conformational stability of poly(L-alanine), poly(L-valine), and poly(L-alanine)/poly(L-valine) blends in the solid state by 13C cross-polarization/magic angle spinning NMR

✍ Scribed by Katsuyoshi Murata; Shigeki Kuroki; Hideaki Kimura; Isao Ando


Publisher
Wiley (John Wiley & Sons)
Year
2002
Tongue
English
Weight
156 KB
Volume
64
Category
Article
ISSN
0006-3525

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Analyses of 13C chemical shielding tensors for powder samples of a-helix-rich poly-L-alanine (pALA) and the mechanically stretched b-sheet pALA Ðlms were performed by solid-state two-dimensional spin-echo (2DSE) NMR spectroscopy. From the iterative Ðtting of 2DSE spectra with spectrum simulations, i