✦ LIBER ✦

A study of chlorinated polyacetylene

✍ Scribed by Franco Cataldo

Publisher: Elsevier Science
Year: 1993
Tongue: English
Weight: 383 KB
Volume: 29
Category: Article
ISSN: 0014-3057
DOI: 10.1016/0014-3057(93)90258-h

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✦ Synopsis

Polyacetylene obtained using Rh(I) complexes was chlorinated both as a film in a gas/solid system and as a suspension in chlorinated solvents. The structures of the products were studied by i.r. and electronic spectroscopy. The presence of unreacted polyene segments and a high degree of stereoregularity in the chlorinated portion was detected. The thermal stability of chlorinated polyacetylene and its chlorine content were investigated by thermogravimetry and differential thermal analysis. The maximum decomposition rate was recorded at 170 ° .

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